The Wizards: Enhanced Edition allow you to live in a fantasy world. But HTC Vive and Oculus Rift could be a better choice than PlayStation VR for this game.
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A good free-to-play MOBA for PS4 and e really good VR game.
Broken Sword 5: The Serpent's Curse is a great point&click adventure, a heir worthy of the first two original game from Revolution Software.
Zone of the Enders: The 2nd Runner M∀RS is (still) the best mecha videogame.
Shenmue is still a great game. A masterpiece in art direction. It's emotions,
Animal Force is a simple VR tower defence, suitable for those who want to approach this genre for the first time, but its party games can give everyone a lot of fun!
Salary Man Escape is a great puzzle game ruined by its useless VR integration.
A great and funny way to enter (literally) in the Rick and Morty universe.
Bravo Team has many limits: it contains few good ideas and a lot of problems. A game with no personality.
Moss is magic. It's an impressive game, not just for the excellent use of PlayStation VR, and at the same time it's the perfect way to spread what VR is capable of.